Roy, Subhash Chandra and Dutta, P. and Nandy, L.N. and Roy, S.K and Samuel, P. (2005) Hydration of 3-cyanopyridine to nicotinamide over MnO2 catalyst. Applied Catalysis A: General , 290 (1-2). pp. 175-180. ISSN 0926-860X

[img] PDF
Restricted to Registered users only

Download (193Kb) | Request a copy

Abstract

A simple and an eco-friendly process for the hydration of 3-cyanopyridine to nicotinamide in the presence of manganese dioxide catalyst has been described. The reaction is conducted at moderate temperature with the reaction times of 5–8 h using an aqueous solution of 3- cyanopyridine. The effect of various reaction parameters on the yield of nicotinamide was studied. In most instances, nearly quantitative yields of amides are obtained without any by-products. The IR and ESCA findings of the catalysts are correlated with the catalytic activity.

Item Type: Article
Uncontrolled Keywords: Catalytic hydration; Nicotinamide; Manganese dioxide catalyst; 3-Cyanopyridine; ESCA; Catalyst recycle
Subjects: Fuel Scinece
Divisions: UNSPECIFIED
Depositing User: Dr. Satyendra Kumar Singh
Date Deposited: 05 Jan 2012 13:12
Last Modified: 05 Jan 2012 13:12
URI: http://cimfr.csircentral.net/id/eprint/589

Actions (login required)

View Item View Item