Gupta, Pavan Kumar and Mahato, Abhishek and Sahu, Gajanan and Maity, Sudip (2021) Fischer-Tropsch synthesis over Pd promoted cobalt based mesoporous supported catalyst. Oil & Gas Science and Technology, 76 (21).
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Abstract. The present study focuses on the catalytic conversion of syngas (CO + H2) through Fischer– Tropsch (FT) route using two identically prepared 0.1 wt.% palladium promoted Mesoporous Alumina (MA) and SBA–15 supported Co (15 wt.%) catalysts. The Fischer–Tropsch activity is performed in a fixed bed tubular reactor at temperature 220 �C and pressure 30 bar with H2/CO ratio ~ 2 having Gas Hourly Space Velocity (GHSV) of 500 h�1 . Detail characterizations of the catalysts are carried out using different analytical techniques like N2 adsorption-desorption, Temperature-programmed reduction with hydrogen (H2-TPR), Temperature-programmed desorption with NH3 (NH3-TPD), X-Ray Diffraction (XRD), and Transmission Electron Microscopy (TEM). The results show that the SBA–15 supported catalyst exhibits higher C6–C12 selectivity (57.5%), and MA supported catalyst facilitates the formation of higher hydrocarbons (C13–C20) having a selectivity of 46.7%. This study attributes the use of both the support materials for the production of liquid hydrocarbons through FT synthesis.
| Item Type: | Article |
|---|---|
| Subjects: | Coal Gesification |
| Divisions: | UNSPECIFIED |
| Depositing User: | Mr. B. R. Panduranga |
| Date Deposited: | 13 Mar 2021 04:54 |
| Last Modified: | 13 Mar 2021 04:54 |
| URI: | http://cimfr.csircentral.net/id/eprint/2342 |
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