Pandey, J.K. (2016) Highly active InOx/TUD-1 catalyst towards Baeyer–Villiger oxidation of cyclohexanone using molecular oxygen and benzaldehyde. Catalysis Communications , 74. pp. 80-84. ISSN 1566-7367

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Abstract

InOx/TUD-1 is prepared by sol–gel method and characterized by different techniques. On the basis of different characterization results it is found that spongy porous InOx/TUD-1 (In/Si=8/100) matrix contains small crystallite of indium oxide in+3 oxidation state. InOx/TUD-1 (In/Si=8/100) catalyst shows good catalytic results for Baeyer–Villiger oxidation of cyclic ketones using molecular oxygen and sacrificial reagent benzaldehyde. The cyclohexanone conversion was found 100% with ε-caprolactone selectivity 100% using polar aprotic solvents e.g. dichloroethane, acetonitrile and benzonitrile in the presence of molecular oxygen.

Item Type:	Article
Uncontrolled Keywords:	InOx/TUD-1; Cyclohexanone; Benzaldehyde; Baeyer–Villiger; Molecular oxygen
Subjects:	Respiratory Protection Laboratory
Divisions:	UNSPECIFIED
Depositing User:	Mr. B. R. Panduranga
Date Deposited:	01 May 2017 04:53
Last Modified:	01 May 2017 04:53
URI:	http://cimfr.csircentral.net/id/eprint/1672

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