Pandey, J.K. (2016) Highly active InOx/TUD-1 catalyst towards Baeyer–Villiger oxidation of cyclohexanone using molecular oxygen and benzaldehyde. Catalysis Communications , 74. pp. 80-84. ISSN 1566-7367

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InOx/TUD-1 is prepared by sol–gel method and characterized by different techniques. On the basis of different characterization results it is found that spongy porous InOx/TUD-1 (In/Si=8/100) matrix contains small crystallite of indium oxide in+3 oxidation state. InOx/TUD-1 (In/Si=8/100) catalyst shows good catalytic results for Baeyer–Villiger oxidation of cyclic ketones using molecular oxygen and sacrificial reagent benzaldehyde. The cyclohexanone conversion was found 100% with ε-caprolactone selectivity 100% using polar aprotic solvents e.g. dichloroethane, acetonitrile and benzonitrile in the presence of molecular oxygen.

Item Type: Article
Uncontrolled Keywords: InOx/TUD-1; Cyclohexanone; Benzaldehyde; Baeyer–Villiger; Molecular oxygen
Subjects: Respiratory Protection Laboratory
Depositing User: Mr. B. R. Panduranga
Date Deposited: 01 May 2017 04:53
Last Modified: 01 May 2017 04:53

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